PROJECT SUMMARY
Sol-gel chemistry
is a popular technique for making new materials and high-technology coatings
of a wide variety of types. Because of the ever-expanding importance of
sol-gel synthesis, and because of the need to make high quality coatings
with a high-throughput industrial procedure, it is important to understand
the fundamentals of spin coating when performed using sol-gel solutions.
Therefore, work has been planned to monitor and understand, in real time,
the coating formation and drying of sol-gel solutions during spin coating.
Dye molecules will be incorporated into the sol-gel solutions to help sense
the chemical and physical changes taking place during spin coating.
Two fundamental
processes are critical in controlling coating formation during spin coating
in general: 1) viscous flow and 2) evaporation. Early stages are dominated
by the viscous behavior, i.e. relatively smooth fluid flow radially outward
on the substrate. As the fluid layer gets thinner the outward flow rate
reduces until the second process (evaporation) takes over as the dominant
process. This transition corresponds to a "setting" point for coating formation.
When spin coating is performed on sol-gel solutions then extra complexities
arise including accelerated chemical reaction caused by solvent evaporation
and viscosity changes being driven by the hydrolysis and condensation reactions
in solution. Thus, sol-gel solutions may be particularly sensitive to the
conditions that are imposed by the spin coating process.
Carefully
designed optical measurements will be carried out which would allow in-depth
study of the dynamical and chemical effects that are occurring in sol-gel
solutions during spin coating. Small concentrations of dye molecules would
be incorporated into the sol-gel solutions for use as structure/chemistry
probes during the spinning process. A thorough literature review has identified
several known dye molecules that can be used to measure water/alcohol mixture
or to probe viscosity increases as gelation occurs within the sol-gel solution.
The primary focus will be on molecules that change their absorption spectra
depending on the characteristics of the local environment. Therefore, equipment
would be set up to allow absorption characteristics to be measured during
spin coating processing. In addition, laser interferometry would be used
to dynamically monitor the rapid fluid thinning process occurring during
spinning.
Throughout
the work, the emphasis will remain focused at learning more about coating
setting, drying, and gelation during the spin coating process. It is anticipated
that increased understanding of this important technological process would
lead to new methods for improving the quality of spin coated sol-gel layers,
thus allowing the production of materials with higher reliability and increased
manufacturing yield. For example, since the evaporation of the most volatile
solution component will dominate during coating formation, then sol-gel
scientists would learn to focus particularly close attention to the chemical
effects caused by early and rapid removal of this component, especially
with respect to premature gelation. And conversely, since the chemical
condensation reactions can cause profound viscosity changes, then coating
developers would seek to understand more about the rheological characteristics
of their sol-gel solutions, even before coating quality issues arise.